The Mechanism of Chromatographic Retention
by RPW Scott
part of the Chrom Ed. Series


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That is V'r(AB) = aV'A + (1-a)V'B (1)

where (V'A) is the retention volume of the solute on the same volume of pure phase (A)
and (V'B) is the retention volume of the solute on the same volume of pure phase (B)

V'AB = a(V'A - V'B) + V'B (2)

This remarkably simple relationship is depicted in figure 9.

Figure 9. Graph of Corrected Retention Volume against Volume Fraction of Stationary Phase

 
 
 

Journal of Chromatographic Science

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