Plate Theory and Extensions
by RPW Scott
part of the Chrom Ed. Series


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Now, if the retention volume of a solute at the outlet pressure (Po) is (Vr(o)) and the true retention volume is (Vr) measured at the mean column pressure (Pr), then

   

                                     PrVr  = PoVr(o)

Thus,                                                                  (24)

It is now necessary to derive an expression for (Pr) and then the correction factor  can be evaluated. The average pressure in the column (Pr) is defined as,          .

 

Now it has been shown that       

  Thus,                                      

 
 
 

Journal of Chromatographic Science

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