Dispersion in Chromatography Columns
by RPW Scott
part of the Chrom Ed. Series


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Now,                                 

                                                                  

or,                                                                   (57)

Again substituting for (B) and (C),

           

                  (58)

Equation (58) shows that the minimum value of (H) is solely dependent on the column radius (r) and the thermodynamic properties of the solute/phase system. As opposed to the optimum velocity, the minimum value of (H) is not dependent on the solute diffusivity.


Related Topics

column diffusivity
 
 
 

Journal of Chromatographic Science

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