Dispersion in Chromatography Columns
by RPW Scott
part of the Chrom Ed. Series


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   or       (25)

Substituting for (Px) from equation (25) in equation (24),

                 (26)

              Let               w =

Then                 or    

Furthermore, when x=0, then and when w = L, then .

Substituting for and  (dx) in  equation (26) and inserting the new limits and integrating,

                       

 or             

Thus,                                                   (27)

Thus, the complete HETP equation for a packed GC column, that takes into account the compressibility of the carrier gas, will be

         (28)

 
 
 

Journal of Chromatographic Science

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