Dispersion in Chromatography Columns
by RPW Scott
part of the Chrom Ed. Series


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Thus,                          and 

 

Substituting for       and   in the HETP equation,

 

 

 

It is now seen that if the mobile phase velocity is taken as that at the column outlet, only the resistance to the mass transfer term for the stationary phase is position dependent. All the other terms can be used as developed by Van Deemter, providing the diffusivities are also measured at the outlet pressure (atmospheric).

 
 
 

Journal of Chromatographic Science

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